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1. To make someone feel annoyed, frustrated, or worried, especially with trivial matters
2. To cause difficulty to and thus puzzle or confuse (someone)
1. The Riddler is known to vex Batman with his complex puzzles and riddles.
2. Tony Stark vexed his fellow Avengers by constantly tinkering with his suits during team meetings.
3. Doraemon was vexed by Nobita's constant demand for gadgets to help him with his homework.
4. Despite being a genius, Sherlock Holmes often found himself vexed by the cleverness of his nemesis, Moriarty.